下列说法或计算正确的是 (     ) A、采用加热蒸发溶剂的方法可

下列说法或计算正确的是 (     )

A、采用加热蒸发溶剂的方法可以使浓度为2mol/L的氢溴酸溶液的浓度变为4mol/L

B、m g H2n g He,在同温同压下密度之比等于m:n

C、只有标准状况下,等物质的量的乙烯和一氧化碳所含的分子数才相等

D、将a%的某物质的水溶液加热蒸发掉m g水(溶质不挥发,且蒸发过程中无溶质析出),所得溶液体积为V L,溶质的质量分数为蒸发前的2倍.设溶质的相对分子质量为M,则蒸发后所得溶液的物质的量浓度为

答案

D


解析:

A错,因为HBr比水容易挥发,所以加热蒸发,浓度更低;

B错,因为ρ=M/V,所以同温同压下ρ(H2)/ρ(He)=Μ(H2)/Μ(He)=2/4=1/2;

C错,根据n=N/NA,物质的量相等,无论在什么条件下分子数都相等;

D正确,蒸发掉m g水溶质的质量分数为蒸发前的2倍,则原来溶液质量为2mg,

n=2m×a%/M mol=am/50M mol,C=n/V=

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