用物质的量都是0.1 mol的HCN和NaCN配成1 L混合溶液,已知其中c(CN-)小于c

用物质的量都是0.1 mol的HCN和NaCN配成1 L混合溶液,已知其中c(CN-)小于c(Na+),则下列判断正确的是(    )

    A.c(H+)>c(OH-)                                   B.c(HCN)+c(CN-)=0.2 mol·L-1

    C.c(Na+)>c(CN-)>c(H+)>c(OH-)         D.c(CN-)>c(OH-)=0.1 mol·L-1

   

答案

解析:混合溶液中存在如下平衡:

    HCN H++CN-,CN-+H2O HCN+OH-,初始时n(HCN)=n(Na+)=n(CN-),配好后c(CN-)小于c(Na+),说明CN-水解程度大于HCN电离程度,溶液显碱性,故c(OH-)>c(H+),答案选B。

    答案:B

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