(10分)t℃时,将2molSO2和1molO2通入体积为2L的恒温恒容密闭容器中,

(10分)t℃时,将2molSO2和1molO2通入体积为2L的恒温恒容密闭容器中,发生如下反应:2SO2(g)+O2(g) 2SO3(g),△H=-196.6kJ/mol. 2min时反应达到化学平衡,此时测得反应物O2还乘余0.8mol,请填写下列空白:

(1)从反应开始到达化学平衡,生成SO3的平均反应速率为          ;平衡时SO2转化率为          

(2)下列叙述能证明该反应已达到化学平衡状态的是(填标号,下同)          

A.溶器内压强不再发生变化

B.SO2的体积分数不再发生变化

C.容器内气体原子总数不再发生变化

D.相同时间内消耗2nmolSO2的同时消耗nmolO­2

E.相同时间内消耗2nmolSO2的同时生成nmolO­2

(3)反应达到化学平衡后,以下操作将引起平衡向正反方向移动并能提高SO2转化率的是          

A.向容器中通入少量O2

B.向容器中通入少量SO2

C.使用催化剂

D.降低温度

E.向容器中通入少量氦气(已知:氦气和SO2、O2、SO3都不发生反应)

(4)t2℃时,若将物质的量之比n(SO2):n(O2)=1:1的混合气体通入一个恒温恒压的密闭容器中,反应达到平衡时,混合气体体积减少了20%。SO2的转化率为          

 

答案

(1) 0.1 mol/(L·min)        20%

(2) A B E

(3) A D

(4)80%

解析:略

 

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