氮化硼(BN)晶体有多种结构,六方相氮化硼是通常存在的稳定相,

氮化硼(BN)晶体有多种结构,六方相氮化硼是通常存在的稳定相,与石墨相似,具有层状结构,有白色石墨之称,具有电绝缘性,可作高温润滑剂。立方相氮化硼是超硬材料,硬度可媲美钻石,常被用作磨料和刀具材料。它们的晶体结构如图所示,关于两种晶体的说法,错误的是

       

                     六方相氮化硼             立方相氮化硼

A.六方相氮化硼属于混合晶体,其层间是靠范德华力维系,所以质地软     

B.立方相氮化硼含有σ键和π键,所以硬度大      

C.六方氮化硼不能导电是因为其层结构中没有自由电子     

D.相同质量的六方相氮化硼和立方相氮化硼所含共价键数不相同

答案

B

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