现有X.Y.Z.W四种常见的含氧酸,其成酸元素分属周期表中短周期

现有X.Y.Z.W四种常见的含氧酸,其成酸元素分属周期表中短周期的第ⅣA族到第 A。将四种含氧酸溶液分别进行光照或微热测得如下数据(其中Q为不确定的物质):

含氧酸

X

Y

Z

W

含氧酸质量/g

25.2

a

3.1

10.5

生成物U/g

3.2

/

/

3.2

生成物V/g

3.6

0.9

0.9

/

生成物Q/g

18.4

3.2

b

c

根据中学所学知识回答下列问题:

(1)上表中含氧酸名称:Z              ,W               ,生成物名称:U              ,V           

(2)上表中数据:a为             ,b为             ,c为            

(3)将X的稀溶液加入Y中,反应的离子方程式是                        

(4)对W的水溶液光照一段时间后,溶液的pH         (填“增大”.“减小”或“不变”)。

答案

(1)Z:碳酸   W:次氯酸  U:氧气   V:水   (各1分)

       (2)a:4.1    b:2.2   c:7.3   (各1分)

       (3)3 H2SO3 +2 NO3 = 3 SO42+2NO↑+4H+H2O   (2分)

       (4)减小   (1分)

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