某科研小组以难溶性钾长石(K2O·Al2O3·6SiO2)为原料,提取Al2O3、K2CO3等

某科研小组以难溶性钾长石(K2O·Al2O3·6SiO2)为原料,提取Al2O3、K2CO3等物质,工艺流程如下:

(1)煅烧过程中有如下反应发生:

①钾长石中的硅元素在CaCO3作用下转化为CaSiO3,写出SiO2转化为CaSiO3的化学方程式:__________________________________

②钾长石中的钾元素和铝元素在Na2CO3作用下转化为可溶性的NaAlO2和KAlO2,写出Al2O3转化为NaAlO2的化学方程式:________________________________。

(2)已知NaAlO2和KAlO2易发生如下水解反应:AlO2+ 2H2OAl(OH)3+OH。“浸取”时应保持溶液呈____性(填“酸”或“碱”),“浸取”时不断搅拌的目的是_______________________________________。

(3)“转化”时加入NaOH的主要作用是(用离子方程式表示)__________________________________________________。

4)上述工艺中可以循环利用的主要物质是 _________ ___________和水。

答案

11(1). CaCO3+SiO2  CaSiO3+CO2

Na2CO3+Al2O3  2NaAlO2+CO2    (2).   提高浸取速率或增大原料浸出率    (3). HCO3+OHH2O+ CO32    (4). Na2CO3  CO2

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