已知:①CH3COOH(l)+2O2(g)===2CO2(g)+2H2O(l) ΔH1; ②C(s)+O2(g)===CO2(g) ΔH2

已知:①CH3COOH(l)+2O2(g)===2CO2(g)+2H2O(l) ΔH1

②C(s)+O2(g)===CO2(g) ΔH2

③2H2(g)+O2(g)===2H2O(l) ΔH3

④2CO2(g)+4H2(g)===CH3COOH(l)+2H2O(l) ΔH4

⑤2C(s)+2H2(g)+O2(g)===CH3COOH(l) ΔH5

下列关于上述反应焓变的判断正确的是(  )

A.ΔH1>0,ΔH2<0                    B.ΔH5=2ΔH2+ΔH3-ΔH1

C.ΔH3>0,ΔH5<0                    D.ΔH4=ΔH1-2ΔH3

答案

解析 乙酸燃烧是放热反应,即ΔH1<0,A错误;根据盖斯定律,反应⑤可由反应2×②+③-①得到,B正确;氢气燃烧放热,即ΔH3<0,C错误;根据盖斯定律,反应④可由反应2×③-①得到,D错误。

答案 B

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