某烷烃和烯烃混合气体的密度是1.07 g·L-1(标准状况),该烷烃和烯

某烷烃和烯烃混合气体的密度是1.07 g·L-1(标准状况),该烷烃和烯烃的体积比为4∶1,则这两种烃是(    )

A.CH4、C2H4                             B.C2H6、C2H4

C.CH4、C4H8                             D.CH4、C3H6

答案

C


解析:

该混合气体的平均摩尔质量为1.07 g·L-1×22.4 L·mol-1=24 g·mol-1,即其平均相对分子质量为24,混合烃中必含CH4,在烃中只有CH4的相对分子质量小于24。

设所含烯烃的相对分子质量为x,

依题意16×+x·=24,

x=56

Mr(CnH2n)=56

14n=56,所以n=4,该烯烃为C4H8

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