25 ℃时,在含有Pb2+、Sn2+的某溶液中,加入过量金属锡(Sn),发生

25 ℃时,在含有Pb2Sn2的某溶液中,加入过量金属锡(Sn),发生反应:

Sn(s)Pb2(aq) Sn2(aq)Pb(s),体系中c(Pb2)c(Sn2)变化关系如图22所示。下列判断正确的是(  )

    A.往平衡体系中加入金属铅后,c(Pb2)增大

B.往平衡体系中加入少量Sn(NO3)2固体后,c(Pb2)变小

C.升高温度,平衡体系中c(Pb2)增大,说明该反应ΔH0

D25 ℃时,该反应的平衡常数K2.2

答案

D

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