将含有杂质的4.0 g的NaOH固体配成1000 mL溶液,取20 mL溶液置于锥形瓶

将含有杂质的4.0 gNaOH固体配成1000 mL溶液,取20 mL溶液置于锥形瓶中,用0.1 mol·L1盐酸滴定(甲基橙作指示剂),消耗盐酸20.4 mL,则该NaOH固体中含有的杂质可能是(  )

ANa2O  BNa2CO3

CNaHCO3  DKOH

答案

答案 A

解析 所消耗盐酸偏多,则所含杂质消耗盐酸比等质量的NaOH所耗盐酸多。

1 g NaOH1 g Na2O1 g Na2CO31 g KOH所耗HCl的物质的量分别为 mol mol mol mol。所以杂质可能是Na2O

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