某500 mL溶液中含0.1 mol Fe2+、0.2 mol Fe3+,加入0.2 mol铁粉,待Fe3+完全还

某500 mL溶液中含0.1 mol Fe2+、0.2 mol Fe3+,加入0.2 mol铁粉,待Fe3+完全还原后,溶液中Fe2+的物质的量浓度为(假设反应前后体积不变)(    )

A.0.4 mol·L-1          B.0.6 mol·L-1            C.0.8 mol·L-1          D.1.0 mol·L-1

答案

解析:2Fe3++Fe3Fe2+,有2 mol Fe3+参加反应,则有3 mol Fe2+生成,现有0.2 mol Fe3+反应,则就有0.3 mol Fe2+生成,加上原溶液Fe2+ 0.1 mol,因此共0.4 mol Fe2+,所以c(Fe2+)=

=0.8 mol·L-1

答案:C


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